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Method for Manufacturing Transition Metal-Deposited Hematite Nanocubes and Nitrophenol Reduction Catalyst Comprising Said Nanocubes

Listed on
2026-10-27
Gold-Palladium Alloy-Supported Hematite Nanocube Nitrophenol Reduction Catalyst Based on Prussian Blue Templates

This technology involves a manufacturing method for obtaining hematite nanocubes embedded with alloy nanoparticles by depositing a gold-palladium alloy onto Prussian blue nanocubes made from metal cyanides, followed by heat treatment, and a nitrophenol reduction catalyst using the same.

p-Nitrophenol, used in the production of dyes, pesticides, and pharmaceuticals, is classified as a priority toxic pollutant by the U.S. EPA, yet it continues to be discharged through industrial wastewater. There has been a lack of catalytic materials capable of efficiently reducing and removing this substance while allowing for repeated use.

This technology creates magnetic hematite catalysts embedded with alloy nanoparticles smaller than 10nm by depositing gold-palladium via galvanic displacement without external reducing or stabilizing agents, followed by heat treatment in air. The synergistic electron transfer between the alloy and hematite effectively reduces nitrophenol, and the catalyst can be recovered using magnetism for multiple reuses. It can be applied to wastewater treatment in dye and pharmaceutical plants, reducing both toxic organic pollutant purification costs and catalyst consumption.

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Key Features:
  • Step of preparing Prussian blue nanocubes by mixing metal cyanides such as potassium hexacyanoferrate in an acidic solution
  • Step of mixing gold and palladium precursors into the Prussian blue nanocube solution to deposit an alloy with a 75:25 molar ratio of gold to palladium
  • Step of performing gold-palladium alloy deposition via galvanic displacement and heat-treating at 300 to 400°C for 4 to 8 hours
  • Nitrophenol reduction catalyst comprising hematite nanocubes obtained by heat-treating Prussian blue with deposited gold-palladium alloy

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Incheon National University
Kyu-Won Kim | Manivannan Shanmugam
Document
Date of application:
2023-02-14
|
Patent registration number:
10-2937189
Industry
advanced materials
environment•eco
Technology
New materials
Chemistry
Country
Korea
Family Patent

N/A

Price
Price negotiable
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