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IBL-26-2345

Polymer and aramid nanofiber composite membrane, method for manufacturing the same, and secondary battery comprising the same

Listed on
2026-10-07
Secondary battery› Material› Separator
Ultra-porous separator combining polar polymers with a 3D aramid nanofiber framework

This technology is a secondary battery separator that combines polymers containing polar functional groups with an aramid nanofiber framework that encapsulates them in a 3D lattice structure. It achieves an ultra-porous structure of over 95% and enhances affinity with electrolytes.

Conventional polyolefin separators have limited energy density due to low porosity and poor electrolyte wettability. In particular, they pose risks of short circuits caused by dendrite growth and thermal runaway when operating lithium metal batteries.

This technology involves coating a mixture of a polymer suspension and aramid nanoseeds, followed by a swelling process through protic solvent exchange and immersion in water to produce a composite membrane with macropores 140–700 nm in diameter. The polar functional groups of the polymer regulate electrolyte wettability and induce the formation of a stable fluorine-based SEI layer, which suppresses dendrite growth. Applicable as a separator for high-energy batteries using lithium metal anodes and high-power power tool cells, it reduces electrolyte impregnation time and minimizes short-circuit risks from high-temperature shrinkage thanks to its heat-resistant skeleton.

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Key Features:
  • Polymers containing polar functional groups, selected from polyvinyl alcohol, polyethylene oxide, polyimide, polyvinylidene fluoride, etc.
  • Aramid nanofiber framework that encapsulates the polar-functionalized polymer and forms the skeleton of the composite membrane
  • Composite membrane with macropores 140 nm to 700 nm in diameter and a porosity of 95.2% to 97.8%
  • Step of preparing a hydrogel by immersing the polymer and aramid nanofiber protic solvent gel in water to swell the polymer and expand the frame

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This invention was developed with support from the Ministry of Science and ICT for the development of 3D nano-skeleton materials applicable to negative electrodes and solid-electrolyte-interphase layers of lithium metal batteries, and in-depth research on suppressing dendrite formation.

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Hanyang University
Bong-Jun Yeom | Dong-Geun Lee
Document
Date of application:
2024-03-18
|
Patent registration number:
10-2921034
Industry
battery
advanced materials
Technology
Energy•Battery
New materials
Country
Korea
Family Patent

WO2025-198302A1

Price
Price negotiable
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