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IBL-26-2147

Method for Manufacturing a Protective Layer on an Anode for Lithium Metal Batteries and the Lithium Metal Battery Anode Manufactured Thereby

Listed on
2026-09-29
Secondary Battery› Battery› Electrode
Artificial SEI for Lithium Metal Anodes Formed via In-Situ Photo/Thermal Polymerization of Liquid Cross-linking Monomers

This technology forms a thin, ion-conductive polymer protective layer (artificial SEI) on a lithium anode by directly applying a liquid cross-linkable monomer to the surface and inducing polymerization through light or heat.

When lithium metal is used as an anode, volume changes during charging and discharging cause the solid electrolyte interphase (SEI) to collapse. This leads to continuous electrolyte decomposition and the growth of dendrites, which reduces battery stability and lifespan.

This technology involves applying a liquid cross-linkable monomer, such as fluorine-containing PEGDA, to the lithium surface and polymerizing it using heat (60–200°C) or 365 nm light. This process simultaneously creates a LiF layer through reaction with the lithium and forms a polymer film. Applicable to anode protection processes for high-energy lithium metal batteries and lightweight, high-capacity cells for drones and UAMs, it suppresses internal resistance increases and delays dendrite formation through simple application and curing, without the need for specialized coating equipment.

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Key Features:
  • Preparing a cross-linkable material in the form of a liquid monomer to form a lithium anode protective layer
  • Directly applying the prepared liquid cross-linkable monomer onto the surface of the lithium anode
  • Applying heat at 60–200°C or 365 nm light to polymerize the cross-linkable material and form the protective layer
  • Liquid poly(ethylene glycol) dimethacrylate cross-linkable material containing fluorine-based components, provided in an amount that achieves a polymerization conversion rate of 50–80%

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Kyungpook National University
Ji-Young Yoo
Document
Date of application:
2020-06-24
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Patent registration number:
10-2680968
Industry
battery
chemicals
Technology
Energy•Battery
Chemistry
Country
Korea
Family Patent

N/A

Price
Price negotiable
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