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IBL-26-2127

Method for Manufacturing Hollow Spherical Lithium Titanium Oxide (LTO) and Hollow Spherical Lithium Titanium Oxide (LTO) Produced Thereby

Listed on
2026-09-29
Secondary Batteries› Materials› Anode Materials
High-Rate, Long-Life Hollow LTO Anode Material Fabricated via Carbon Nanosphere Template Hydrothermal Synthesis

This technology involves depositing amorphous lithium titanium oxide (LTO) nanoparticles onto the surface of spherical carbon templates via hydrothermal synthesis, followed by heat treatment in an oxidizing atmosphere at 500–700°C to remove the carbon, resulting in a hollow spherical LTO structure.

Conventional LTO synthesis processes often suffer from particle growth during high-temperature sintering, which reduces the specific surface area and degrades high-rate charge/discharge performance. Furthermore, using amorphous LTO presents challenges in securing lithium-ion diffusion pathways due to low crystallinity.

By forming a hollow structure through the deposition of nanoparticles onto carbon templates, this technology increases the contact area with the electrolyte. Additionally, by optimizing the heat treatment temperature to around 600°C, it achieves a balance between crystallinity and particle size. Applicable as an anode material for both lithium-ion batteries and lithium-ion capacitors, it is highly valuable for high-power applications, maintaining over 90% of its initial capacity after 1,000 cycles even at 10C.

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Key Features:
  • Forming lithium titanium oxide (Li4Ti5O12) nanoparticles via hydrothermal synthesis of a mixed LiO2 and LiOH solution
  • Forming a template composite with deposited nanoparticles by hydrothermally synthesizing a mixture of LTO nanoparticles and spherical carbon templates at 160–200°C
  • Removing the carbon template by heat-treating the nanoparticle-deposited composite in an oxidizing atmosphere at 500–700°C
  • Pre-forming spherical carbon templates by hydrothermally synthesizing a glucose solution at 180–200°C for 3–5 hours

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Kyungpook National University
Sang-eun Jeon | Su-hyeok Choi
Document
Date of application:
2024-06-13
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Patent registration number:
10-2769200
Industry
battery
advanced materials
Technology
Energy•Battery
New materials
Country
Korea
Family Patent

N/A

Price
Price negotiable
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