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IBL-26-2073

Polymer solid electrolyte and all-solid-state battery containing the same

Listed on
2026-09-29
Secondary Battery› Materials› Electrolyte
Polymer electrolyte with enhanced room-temperature ionic conductivity via the addition of imidazolium-based organic ionic plastic crystals

This technology is a polymer solid electrolyte that improves the low ionic conductivity and electrochemical instability of conventional polymer electrolytes by incorporating imidazolium-based organic ionic plastic crystals (OIPC), which remain in a solid state at room temperature, into an ion-conductive polymer matrix.

Conventional polymer solid electrolytes have faced challenges in commercialization due to lower ionic conductivity and lithium-ion transference numbers compared to liquid or inorganic electrolytes. Furthermore, when used with lithium metal anodes, they suffer from dendrite growth, which reduces battery lifespan.

This technology involves creating an electrolyte by mixing an ion-conductive polymer, such as polyalkylene oxide, with organic ionic plastic crystals composed of imidazolium cations and halogen anions (Cl-, Br-, I-), along with a lithium salt. This achieves an ionic conductivity of 1.0x10^-3 S/cm or higher at room temperature and stabilizes the interface with the lithium metal anode. It can be applied to all-solid-state batteries using lithium metal anodes and power sources for wearable and flexible devices that are free from leakage risks, accelerating the design of polymer all-solid-state cells capable of operating at room temperature without the need for external heating.

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Key Features:
  • Polymer solid electrolyte containing an ion-conductive polymer, imidazolium cation and halogen anion-based organic ionic plastic crystals, and a lithium salt
  • Organic ionic plastic crystals included at 0.5 to 5 parts by weight per 100 parts by weight of the ion-conductive polymer
  • Step of preparing a mixed solution by combining organic ionic plastic crystals and a lithium salt in an organic solvent
  • Step of adding the ion-conductive polymer to the mixed solution, coating the resulting slurry onto a substrate, and drying and heating to obtain the electrolyte

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DGIST
Jae-Hyun Kim | Eun-Hee Kim | Hassan Jamal | In-Jun Jeon
Document
Date of application:
2023-08-03
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Patent registration number:
10-2840238
Industry
battery
chemicals
Technology
Energy•Battery
Chemistry
Country
Korea
Family Patent

US2026-0204637A1, WO2025-028858A1

Price
Price negotiable
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